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BWIN·必赢(中国)唯一官方网站

姓名 刘斌 

性别

职称 特聘教授

学位 博士

专业有机化学

电子邮箱liubin@ncu.edu.cn

研究方向 过渡金属催化,自由基化学

教育工作经历

教育背景

博士2009.9-2014.7 浙江大学 有机化学 导师:史炳锋 教授

本科 2005.9-2009.7 bwin必赢唯一官方网站 应用化学

工作经历

2021-至今:bwin必赢唯一官方网站,特聘教授

2019.01-2021 Research Scientist II 科罗拉多州立大学,美国 (Colorado State University) 导师:Garret M. Miyake

2017.08-2018.12博士后 科罗拉多州立大学,美国 (Colorado State University) 导师:Garret M. Miyake

2016.05-2017.08 博士后 科罗拉多大学博尔德分校,美国 (University of Colorado Boulder) 导师:Garret M. Miyake

2014.09-2016.04 博士后 浙江大学 导师: 史炳锋/崔孙良 教授

教学简介

科研简介详情请看课题组主页:https://www.x-mol.com/groups/liu_bin

欢迎本科生加入课题组从事科研训练欢迎对本课题组感兴趣的研究生报考,联系方式:理科生命大楼B859

代表性论文及专利

  1. Bin Liu, Andrew M. Romine, Camille Z. Rubel, Keary M. Engle, and Bing-Feng Shi Chelation-Assisted, Transition-Metal-Catalyzed Functionalization of Inert C(sp3)–H Bonds. Chem. Rev. 2021. 121, 14957–15074.

  1. Liu, B.; Elder, W. Z.; Miyake, G. M. Scalable and Phosphine-Free Conversion of Alcohols to Carbon–Heteroatom Bonds through the Blue Light-Promoted Iodination Reaction. J. Org. Chem. 2020. 85, 3717–3727. (One of the most read articles, March 2020)

  1. Liu, B.; Alegre-Requena, J.; Paton, R.; Miyake, G. M. Unconventional Reactivity of Ethynylbenziodoxolone (EBX) Reagents and Thiols: Scope and Mechanism. Chem. Eur. J. 2020, 26, 2386 –2394. (Inside Cover, hot paper)

  1. Liu, B.; Lim, C.-H.; Miyake, G. M. Light driven intermolecular charge transfer induced reactivity of ethynylbenziodoxol(on)e (EBX) and phenols. J. Am. Chem. Soc. 2018, 140, 12829−12835.

  1. Lim, C.-H.; Kudisch, M.; Liu, B.; Miyake, G. M. C–N Cross-Coupling via Photoexcitation of Nickel–Amine Complexes. J. Am. Chem. Soc. 2018, 140, 7667–7673.

  1. Liu, B.; Lim, C.-H.; Miyake, G. M. Transition-Metal-Free, Visible-Light-Promoted C–S Cross-Coupling through Intermolecular Charge Transfer. Synlett 2018, 29, 2449−2455.

  1. Liu, B.; Lim, C.-H.; Miyake, G. M. Visible Light-Promoted C-S Cross-Coupling via Intermolecular Charge-Transfer. J. Am. Chem. Soc. 2017, 139, 13616–13619. (1 most read article, October 2017, highlighted in SYNFACTS)

  1. Liu, B.; Zhang, Z.-Z.; Li, X.; Shi, B.-F. Nickel(II)-Catalyzed Direct Arylation of Aryl C–H Bonds with Aryl-boron Reagents Directed by a Removable Bidentate Auxiliary. Org. Chem. Front. 2016, 3, 897−900.

  1. Liu, B.; Shi, B.-F. γ-Lactone Synthesis via Palladium(II)-Catalyzed Lactonization of Unactivated Methylene C(sp3)–H Bonds. Synlett 2016, 27, 2396–2400.

  1. Zhang, Z.-Z.; Liu, B.; Xu, J.-W.; Yan, S.-Y.; Shi, B.-F. Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes. Org. Lett. 2016, 18, 1776−1779.

  1. Zhao, S.; Liu, B.; Zhan, B.-B.; Zhang, W.-D.; Shi, B.-F. Nickel-Catalyzed Ortho-Arylation of Unactivated (Hetero)aryl C–H Bonds with Arylsilanes Using a Removable Auxiliary. Org. Lett. 2016, 18, 4586−4589.

  1. Liu, B; Shi, B.-F. Transition-Metal-Catalyzed Etherification of Unactivated C-H Bonds. Tetrahedron Lett. 2015, 56, 15−22.

  1. Liu, B.; Hu, F.; Shi, B.-F. Recent Advances on Ester Synthesis via Transition-Metal-Catalyzed C-H Activation. ACS Catalysis 2015, 5, 1863−1881.

  1. Yan, S.-Y.; Liu, Y.-J.; Liu, B.; Liu, Y-H.; Shi, B.-F. Nickel-Catalyzed Thiolation of Unactivated Aryl C–H Bonds: An Efficient Access to Diverse Aryl Sulfides. Chem. Commun. 2015, 51, 4069–4072.

  1. Li, B.; Liu, B.; Shi, B.-F. Copper-Catalyzed ortho-Halogenation of Arenes and Heteroarenes Directed by a Removable Auxiliary. Chem. Commun. 2015, 51, 5093–5096.

  1. Yan S.-Y.; Liu Y.-J.; Liu B.; Liu Y-H.; Zhang Z-Z.; Shi, B.-F. Nickel-Catalyzed Direct Thiolation of Unactivated C(sp3)-H Bonds with Disulfides. Chem. Commun. 2015, 51, 7341–7344.

  1. Zhan, B.-B.; Liu, B.; Shi, B.-F. Recent Progress on Nickel-Catalyzed Direct Functionalization of Unactivated C-H Bonds (in Chinese). Chin. Sci. Bull. 2015, 60, 1–11.

  1. Zhang, Z.-Z.; Liu, B.; Wang, C-Y.; Shi, B.-F. Cobalt(III)-Catalyzed C2-Selective C-H Alkynylation of Indoles. Org. Lett. 2015, 17, 4094–4097.

  1. Zhao, S.; Chen, F-J.; Liu, B.; Shi, B.-F. Copper-Catalyzed Direct Acyloxylation of C(sp2)-H Bonds with Benzoic Acids. SCIENCE CHINA Chemistry, 2015, 58, 1302–1309.

  1. Li, B.; Wang, S-Q.; Liu, B.; Shi, B.-F. Synthesis of Oxazolines from Amides via Palladium-Catalyzed Functionalization of Unactivated C(sp3)-H Bond. Org. Lett. 2015, 17, 1200–1203.

  1. Liu, B.; Jiang, H.-Z.; Shi, B.-F. Palladium-Catalyzed Oxidative Olefination of Phenols Bearing Removable Directing Groups under Molecular Oxygen. J. Org. Chem. 2014, 79, 1521–1526.

  1. Liu, B.; Jiang, H.-Z.; Shi, B.-F. Palladium-Catalyzed Oxidative Alkoxy- carbonylation of 2-Phenoxypyridine Derivatives with CO and Alcohols. Org. Biomol. Chem. 2014, 12, 2538–2542.

  1. Liu, B.; Hu, F.; Shi, B.-F. Synthesis of Sterically Congested Polycyclic Aromatic Hydrocarbons: Rh(III)-Catalyzed Cascade Oxidative Annulation of Aryl Ketoximes with Internal Alkynes by Sequential Cleavage of Multiple C-H Bonds. Adv. Synth. Catal. 2014, 356, 2688–2696.

  1. Zhang, B.; Guan, H.-X.; Liu, B.; Shi, B.-F. Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)-H Bonds Assisted by Bidentate Directing Groups. Chin. J. Org. Chem. 2014, 34, 1487–1498.

  1. Liu, B.; Shi, B.-F. Efficient Synthesis of Carboxylic Esters via Pd(II)-Catalyzed Direct Alkoxycarbonylation of Arenes with CO and Alcohols. Synlett 2013, 24, 2274–2278.

编写章节

  1. Liu, B.; Hu, F.; Shi, B-F. Rh-Catalyzed Synthesis of Oxygen-Containing Heterocycles (chapter 6). Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation, (Invited chapter), X. F. Wu (Ed.), Wiley, 2016, pp 161-186.

  2. Liu, B.; Han, Y.-Q.; Shi, B.-F. Palladium-Catalyzed Arylation of Unactivated sp3 C-H Bond. Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization (Debabrata Maiti and Anant Kapdi, Eds), Elsevier, 2017, pp 167-203.

  3. Yan, S.-Y.; Liu, B.; Shi, B.-F. Substrate-Controlled Transformation– Diastereoselective Functionalization in C-H Activation for Asymmetric Synthesis (Eds: Colobert, F.; Wencel-Delord, J.), Wiley-VCH, Weinheim, September 2019, pp 107-130

申请专利

  1. Miyake, G. M.; Liu, B.; Lim, C.-H. Photocatalyst-free, light-induced carbon-sulfur cross-coupling methods. US20180370911A1.

  2. Miyake, G. M.; Lim, C.-H.; Kudisch, M.; Liu, B. Methods for forming aryl carbon-nitrogen bonds using light and photoreactors useful for conducting such reactions. US20190345122A1.