Name: Qinglong Zhang

Gender: male

Job title: Distinguished Research Fellow

Email Address: zhangqinglong@ncu.edu.cn

Education and Work Experience ：

2023.07 -- present: School of Chemistry and Chemical Engineering, Nanchang University,

2017.09~2023.06: Nankai University, Postdoctoral Scholar, advisor: Prof. Weiwei Zi

2012.09~2017.06: Nankai University, doctoral degree, advisor: Prof. You Huang

2008.09~2012.06: Shandong University of Science and Technology, bachelor's degree, advisor: Prof. Peng Wang

Teaching：

Research fields: Organic Synthesis and Asymmetric Catalysis

Research projects：

National Natural Science Foundation of China (no. 22001130)

China Postdoctoral Science Foundation (no. 2019M660973)

Awards and Honors：

Representative papers and patents：

Papers:

1. Qinglong Zhang, Minghui Zhu, Weiwei Zi* Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates Chem 2022, 8, 2784-2796.

2. Huimin Yu, Qinglong Zhang*, Weiwei Zi* Enantioselective Three-Component Photochemical 1,4-Bisalkylation of 1,3-Butadiene with Pd/Cu Catalysis Angew. Chem. Int. Ed. 2022, 61，e202208411. （Hot Paper，Frontispiece ）

3. Minghui Zhu,# Qinglong Zhang,# Weiwei Zi* Diastereodivergent Synthesis of β-Amino Alcohols by Dual-Metal-Catalyzed Coupling of Alkoxyallenes with Aldimine Esters Angew. Chem. Int. Ed. 2021, 60, 6545-6552. （# equal contribution）

4. Qinglong Zhang, Dongfang Dong, Weiwei Zi* Palladium-Catalyzed Regio- and Enantioselective Hydrosulfonylation of 1,3-Dienes with Sulfinic Acids: Scope, Mechanism, and Origin of Selectivity J. Am. Chem. Soc. 2020, 142, 15860–15869.

5. Qinglong Zhang,# Huimin Yu,# Lulu Shen, Tianhua Tang, Dongfang Dong, Weiwei Chai, Weiwei Zi* Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis J. Am. Chem. Soc. 2019, 141, 14554–14559. （#：equal contribution）

6. Qinglong Zhang, Hongxing Jin, Jiaxu Feng, Yannan Zhu, Penghao Jia, Chengzhou Wu, You Huang* Sequential Phosphine-Catalyzed [4 + 2] Annulation of β′-Acetoxy Allenoates: Enantioselective Synthesis of 3-Ethynyl-Substituted Tetrahydroquinolines Org. Lett. 2019, 21, 1407-1411.

7. Qinglong Zhang, Yannan Zhu, Hongxing Jin, You Huang* A phosphine mediated sequential annulation process of 2-tosylaminochalcones with MBH carbonates to construct functionalized aza-benzobicyclo[4.3.0] derivatives Chem. Commun. 2017, 53, 3974-3977.

8. Minghui Zhu, Peixin Wang, Qinglong Zhang, Wenjun Tang *, Weiwei Zi* Diastereodivergent Aldol-Type Coupling of Alkoxyallenes with Pentafluorophenyl Esters Enabled by Synergistic Palladium/Chiral Lewis Base Catalysis Angew. Chem. Int. Ed. 2022, 61，e202207621.

9. Huimin Yu, Qinglong Zhang, Weiwei Zi* Synergistic Pd/Cu-catalyzed enantioselective Csp2–F bond alkylation of fluoro-1,3-dienes with aldimine esters Nat. Commun. 2022, 13, 2470.

10. Weiwei Chai, Bin Guo, Qinglong Zhang, Weiwei Zi* Cooperative Pd/Cu-catalyzed diastereodivergent coupling of allenamides and aldimine esters to access the Mannich-type motifs Chem Catalysis 2022, 2, 1428-1439.

11. Hongfa Wang, Ruiyuan Zhang, Qinglong Zhang, Weiwei Zi* Synergistic Pd/Amine-Catalyzed Stereodivergent Hydroalkylation of 1,3-Dienes with Aldehydes: Reaction Development, Mechanism, and Stereochemical Origins J. Am. Chem. Soc. 2021, 143, 10948–10962.

12. Penghao Jia, Qinglong Zhang, Qima Ou, and You Huang* Sequential [1 + 4]- and [2 + 3]-Annulation of Prop-2-ynylsulfonium Salts: Access to Hexahydropyrrolo[3,2-b]indoles Org. Lett. 2017, 19, 4664-4667.

13. Penghao Jia, Qinglong Zhang, Yuzhou Zhuge, Xingyue Liwei, You Huang* One-Pot Synthesis of Cyclopropanes from Methylene Azabicyclo[3.1.0]hexanes Obtained by Formal Sequential [1+2]- and [2+3]-Cycloaddition Reaction of Prop-2-ynylsulfonium Salts and Tosylaminomethyl Enones Adv. Synth. Catal. 2018, 360, 438-443.

14. Penghao Jia, Qinglong Zhang, Hongxing Jin, You Huang* [3 + 2]-Annulation of Prop-2-ynylsulfonium Salts: Access to Hydroindol-5-ones Containing a Methylthio Group Org. Lett., 2017, 19, 412-415.

15. Hongxing Jin, Qinglong Zhang, Erqing Li, Penghao Jia, Ning Li, You Huang* Phosphine-catalyzed intramolecular Rauhut–Currier reaction: enantioselective synthesis of hydro-2H-indole derivatives Org. Biomol. Chem. 2017, 15, 7097−7101.

16. Chongchong Hu, Qinglong Zhang, You Huang* Phosphine-Catalyzed Rauhut–Currier Domino Reaction: A Facile Strategy for the Construction of Carbocyclic Spirooxindoles Skeletons Chem. Asian J. 2013, 8, 1981-1984.

Patents：

1. 资伟伟，张庆龙，立体多样性合成α，β-二取代-4-戊烯酸衍生物的方法，专利申请号：CN202210432651.2