Name: Tao Yang
Gender: Male
Job title: Prof. Dr.
Email Address: chmyt@ncu.edu.cn
Education and Work Experience:
2021.06-- present: School of Chemistry and Chemical Engineering, Nanchang University, Professor
2018.11-2021.1, National University of Singapore,Postdoctoral,Supervisor: Prof. MingJoo Koh
2016.8-2018.11, South University of Science and Technology of China, Postdoctoral, Supervisor: Prof. Xumu Zhang
2011.9-2016.7, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, PhD degree, Supervisor: Prof. Long Lv and Qilong Shen
2007.9-2011.6, Shanghai University, Bachelor's degree, Supervisor: Prof. Hegui Gong
Teaching:Organic Chemistry and College Chemistry
Research fields: Organic synthesis, asymmetric catalysis, fluorine chemistry, photochemistry, dual transition metal–visible light photoredox catalysis.
Research projects:
1. Start-up Fund of Nanchang University, 1,500,000(CNY), 2021-2026.
2. National Natural Science Foundation of Jiangxi Province, 100,000(CNY),2023-2024;
3. "Double Thousand Plan" Talent Project of Jiangxi Province, 1,000,000(CNY),2023-2027;
Awards and Honors:
Representative papers and patents:
(1) Yang, T. #; Wei, Y. #; Koh, M. J.* Photoinduced Nickel-Catalyzed Deaminative Cross-Electrophile Coupling for C(sp2)–C(sp3) and C(sp3)–C(sp3) Bond Formation. ACS Catal. 2021, 11, 6519. (# co-first authors)
(2) Yang, T. #; Jiang, Y. #; Luo, Y.; Lan, Y.*; Koh, M. J.* Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation. J. Am. Chem. Soc. 2020, 142, 21410. (# co-first authors)
(3) Yang, T.; Chen, X.; Rao, W.; Koh, M. J.* Broadly Applicable Directed Catalytic Reductive Difunctionalization of Alkenyl Carbonyl Compounds. Chem 2020, 6, 738.
(4) Chen, X.; Rao, W.; Yang, T.*; Koh, M. J.* Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation. Nat. Commun. 2020, 11, 5857.
(5) Wang, X. #; Yang, T. #; Cheng, X.; Shen, Q.* Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis. Angew. Chem. Int. Ed. 2013, 52, 12860–12864. (# co-first authors)
(6) Yin, C. #; Yang, T. #; Pan, Y.; Wen, J.*; Zhang, X.* Rh-Catalyzed Asymmetric Hydrogenation of Unsaturated Medium-Ring NH Lactams: Highly Enantioselective Synthesis of N-Unprotected 2,3-Dihydro-1,5-benzothiazePin
ones. Org. Lett. 2020, 22, 920–923. (# co-first authors)
(7) Yang, T.; Guo, X.; Yin, Q.*; Zhang, X.* Intramolecular asymmetric reductive amination: synthesis of enantioenriched dibenz[c,e]azepines. Chem. Sci. 2019, 10, 2473–2477.
(8) Yang, T.; Yin Q.; Gu, G.; Zhang, X.* A one-pot process for the enantioselective synthesis of tetrahydroquinolines and tetrahydroisoquinolines via asymmetric reductive amination (ARA). Chem. Commun. 2018, 54, 7247–7250.
(9) Yang, T.; Lu, L.*; Shen Q.* Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes. Chem. Commun. 2015, 51, 5479–5481.
(10) Yang, T.; Shen, Q.*; Lu, L.* Chincona Alkaloid-Catalyzed Enantioselective Trifluoromethylthiolation of Oxindoles. Chinese Journal of Chemistry 2014, 32, 678–680.
(11) Jiang, Y.; Pan, J.; Yang, T.; Zhao, Y.; Koh, M. J. Nickel-catalyzed site- and stereoselective reductive alkylalkynylation of alkynes. Chem, 2021, DOI: 10.1016/j.chem pr.2020.12.024.
(12) Shao, X.; Wang, X.; Yang, T.; Lu, L.*; Shen, Q.* An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation. Angew. Chem. Int. Ed. 2013, 52, 3457– 3460.
(13) Yu, X.; Yang, T.; Wang S.; Xu H.; Gong, H. Nickel-Catalyzed Reductive Cross-Coupling of Unactivated Alkyl Halides. Org. Lett. 2011,13, 2138–2141.
Patent
Qilong Shen、Long Lv、Xinxin Shao、Xueqiang Wang、Tao Yang. Synthesis and application of an electrophilic SCF3 reagent China No. ZL201210460539.6.
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